Publications

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2017


185.

Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd-Bi-Te/C (PBT/C) Catalyst

Ahmed, M.S.; Mannel, D.S.; Root, T.W.; Stahl, S.S. Org. Process Res. Dev. 2017, Article ASAP.
10.1021/acs.oprd.7b00223

184.

Non-Covalent Immobilization of Molecular Electrocatalysts for Chemical Synthesis: Efficient Electrochemical Alcohol Oxidation with a Pyrene-TEMPO Conjugate

Das, A.; Stahl, S.S. Angew. Chem. Int. Ed. 2017, 56, 8892-8897.
10.1002/anie.201704921 PDF icon Supporting Info.pdf

183.

Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes

Vasilopoulos, A.; Zultanski, S.L.; Stahl, S.S. J. Am. Chem. Soc. 2017, 139, 7705-7708.
10.1021/jacs.7b03387 PDF icon Supporting Info.pdf

182.

Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)2 and Discovery of Fe(OTf)3 as a Highly Effective Cocatalyst

Wang, D.; Stahl, S. S. J. Am. Chem. Soc. 2017, 139, 5704-5707.
10.1021/jacs.7b01970 PDF icon Supporting Info.pdf

181.

Characterization of NiFe oxyhydroxide electrocatalysts by integrated electronic structure calculations and spectroelectrochemistry

Goldsmith, Z. K.; Harshan, A. K.; Gerken, J. B.; Vörös, M.; Galli, G.; Stahl, S. S.; Hammes-Schiffer, S. Proc. Natl. Acad. Sci. U.S.A. 2017, 114, 3050-3055.
10.1073/pnas.1702081114 PDF icon Supporting Info.pdf

180.

Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diamine Precursor into a Highly Active Aerobic Oxidation Catalyst

McCann, S. D.; Lumb, J. -P.; Arndtsen, B. A.; Stahl, S. S. ACS Cent. Sci. 2017, 3, 314-321.
10.1021/acscentsci.7b00022 PDF icon Supporting Info.pdf

179.

Detection of Palladium(I) in Aerobic Oxidation Catalysis

Jaworski, J. N.; McCann, S. D.; Guzei, I. A.; Stahl, S. S. Angew. Chem., Int. Ed. 2017, 56, 3605-3610.
10.1002/anie.201700345 PDF icon Supporting Info.pdf

178.

Discovery of Multicomponent Heterogeneous Catalysts via Admixture Screening: PdBiTe Catalysts for Aerobic Oxidative Esterification of Primary Alcohols

Mannel, D. S.; Ahmed, M. S.; Root, T. W.; Stahl, S. S. J. Am. Chem. Soc. 2017, 139, 1690-1698.
10.1021/jacs.6b12722 PDF icon Supporting Info.pdf

177.

Co/NHPI-mediated aerobic oxygenation of benzylic C–H Bonds in pharmaceutically relevant molecules

Hruszkewycz, D. P.; Miles, K. C.; Thiel, O. R.; Stahl, S. S. Chem. Sci. 2017, 8, 1282-1287.
10.1039/C6SC03831J PDF icon Supporting Info

2016


176.

Quinone 1 e- and 2 e-/2 H+ Reduction Potentials: Identification and Analysis of Deviations from Systematic Scaling Relationships

Huynh, M. T.; Anson, C. W.; Cavell, A. C.; Stahl, S. S.; Hammes-Schiffer, S. J. Am. Chem. Soc. 2016, 138, 15903–15910.
10.1021/jacs.6b05797 PDF icon Supporting Info

175.

Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products

Iosub, A. V.; Stahl, S. S. ACS. Catal. 2016, 6, 8201-8213.
10.1021/acscatal.6b02406

174.

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

Zhang, W.; Wang, F.; McCann, S. D.; Wang, D.; Chen, P.; Stahl, S. S.; Liu, G. Science 2016, 353, 1014-1018.
10.1126/science.aaf7783 PDF icon Supporting Info

173.

KetoABNO/NOx Cocatalytic Aerobic Oxidation of Aldehydes to Carboxylic Acids and Access to α-Chiral Carboxylic Acids via Sequential Asymmetric Hydroformylation/Oxidation

Miles, K. C.; Abrams, L. M.; Landis, C. R.; Stahl, S. S. Org. Lett. 2016, 18, 3590–3593.
10.1021/acs.orglett.6b01598 PDF icon Supporting Info

172.

Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C–H Bonds

Clagg, K.; Hou, H.; Weinstein, A. B.; Russell, D.; Stahl, S. S.; Koenig, S. G. Org. Lett. 2016, 18, 3586–3589.
10.1021/acs.orglett.6b01592 PDF icon Supporting Info

171.

Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators

Badalyan, A.; Stahl, S. S. Nature 2016, 535, 406–410.
10.1038/nature18008 PDF icon Supporting Info

170.

Practical Synthesis of Amides via Copper/ABNO-Catalyzed Aerobic Oxidative Coupling of Alcohols and Amines

Zultanski, S. L.; Zhao, J.; Stahl, S. S. J. Am. Chem. Soc. 2016, 138, 6416–6419.
10.1021/jacs.6b03931 PDF icon Supporting Info

169.

Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions

White, P. B.; Jaworski, J. N.; Geyunjian, H. Z.; Stahl, S. S. ACS Catal. 2016, 6, 3340-3348.
10.1021/acscatal.6b00953 PDF icon Supporting Info

168.

Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions

White, P. B.; Jaworski, J. N.; Fry, C. G.; Dolinar, B. S.; Guzei, I. A.; Stahl, S. S. J. Am. Chem. Soc. 2016, 138, 4869-4880.
10.1021/jacs.6b01188 PDF icon Supporting Info

167.

Co(salophen)-Catalyzed Aerobic Oxidation of p-Hydroquinone: Mechanism and Implications for Aerobic Oxidation Catalysis

Anson, C. W.; Ghosh, S.; Hammes-Schiffer, H.; Stahl, S. S. J. Am. Chem. Soc. 2016, 138, 4186-4193.
10.1021/jacs.6b00254 PDF icon Supporting Info

166.

Discovering Inexpensive, Effective Catalysts for Solar Energy Conversion: An Authentic Research Laboratory Experience

Shaner, S. E.; Hooker, P. D.; Nickel, A.-M.; Leichtfuss, A. R.; Adams, C. S.; de la Cerda, D.; She, Y.; Gerken, J. B.; Pokhrel, R.; Ambrose, N. J.; Khaliqi, D.; Stahl, S. S.; Schuttlefield Christus, J. D. J. Chem. Ed. 2016, 93, 650-657.
10.1021/acs.jchemed.5b00591 PDF icon Supporting Info

165.

Mechanism of Copper/Azodicarboxylate-Catalyzed Aerobic Alcohol Oxidation: Evidence for Uncooperative Catalysis

McCann, S. D.; Stahl, S. S. J. Am. Chem. Soc. 2016, 138, 199-206.
10.1021/jacs.5b09940 PDF icon Supporting Info

2015


164.

Operando Analysis of NiFe and Fe Oxyhydroxide Electrocatalysts for Water Oxidation: Detection of Fe4+ by Mössbauer Spectroscopy

Chen, J. Y. C.; Dang, L.; Liang, H.; Bi, W.; Gerken, J. B.; Jin, S.; Alp, E. E.; Stahl, S. S. J. Am. Chem. Soc. 2015, 137, 15090-15093.
10.1021/jacs.5b10699 PDF icon Supporting Info

163.

Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects

Rafiee, M; Miles, K. C.; Stahl, S. S. J. Am. Chem. Soc. 2015, 137, 14751–14757.
10.1021/jacs.5b09672 PDF icon Supporting Info

162.

Quinone-Catalyzed Selective Oxidation of Organic Molecules

Wendlandt, A. E.; Stahl, S. S. Angew. Chem. Int. Ed. 2015, 54, 14638-14658.
10.1002/anie.201505017

161.

Stable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl-Catalyzed Aerobic Alcohol Oxidation

Steves, J. E.; Stahl, S. S. J. Org. Chem. 2015, 80, 11184–11188.
10.1021/acs.joc.5b01950 PDF icon Supporting Info

160.

Catalytic Aerobic Dehydrogenation of Nitrogen Heterocycles Using Heterogeneous Cobalt Oxide Supported on Nitrogen-Doped Carbon

Iosub, A. V.; Stahl, S. S. Org. Lett. 2015, 17, 4404-4407.
10.1021/acs.orglett.5b01790 PDF icon Supporting Info

159.

High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis

Gerken, J. B.; Stahl, S. S. ACS Cent. Sci. 2015, 1, 234-243.
10.1021/acscentsci.5b00163 PDF icon Supporting Info

158.

Process Development of CuI/ABNO/NMI-Catalyzed Aerobic Alcohol Oxidation

Steves, J. E.; Preger, Y.; Martinelli, J. R.; Welch, C. J.; Root, T. W.; Hawkins, J. M.; Stahl, S. S. Org. Process Res. Dev. 2015, 19, 1548–1553.
10.1021/acs.oprd.5b00179 PDF icon Supporting Info

157.

Regioselective Aerobic Oxidative Heck Reactions with Electronically Unbiased Alkenes: Efficient Access to α-Alkyl Vinylarene

Zheng, C.; Stahl, S. S. Chem. Commun. 2015, 51, 12771–12774.
10.1039/C5CC05312A PDF icon Supporting Info

156.

The “Best Catalyst” for Water Oxidation Depends on the Oxidation Method Employed: A Case Study of Manganese Oxides

Pokhrel, R.; Goetz, M. K.; Shaner, S. E.; Wu X.; Stahl, S. S. J. Am. Chem. Soc. 2015, 137, 8384–8387.
10.1021/jacs.5b05093 PDF icon Supporting Info

155.

PTFE-Membrane Flow Reactor for Aerobic Oxidation Reactions and Its Application to Alcohol Oxidation

Greene, J. F.; Preger, Y.; Stahl, S. S.; Root, T. W. Org. Process Res. Dev. 2015, 19, 858–864.
10.1021/acs.oprd.5b00125

154.

Copper-Catalyzed Aerobic Oxidations of Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron Oxidant and a One-Electron Redox-Active Catalyst

McCann, S. D.; Stahl, S. S. Acc. Chem. Res. 2015, 48, 1756–1766.
10.1021/acs.accounts.5b00060

153.

Palladium-catalyzed aerobic acetoxylation of benzene using NOx-based redox mediators

Zultanski, S. L.; Stahl, S. S. J. Organomet. Chem. 2015, 793, 263-268.
10.1016/j.jorganchem.2015.03.003

152.

Practical Aerobic Alcohol Oxidation with Cu/Nitroxyl and Nitroxyl/NOx Catalyst Systems

Miles, K. C.; Stahl, S. S. Aldrichimica Acta 2015, 48, 8-10.
PDF icon Volume 48

151.

Efficient and Selective Cu/Nitroxyl-Catalyzed Methods for Aerobic Oxidative Lactonization of Diols

Xie, X.; Stahl, S. S. J. Am. Chem. Soc. 2015, 137, 3767–3770.
10.1021/jacs.5b01036 PDF icon Supporting Info

150.

Palladium-Catalyzed Aerobic Oxidative Dehydrogenation of Cyclohexenes to Substituted Arene Derivatives

Iosub, A. V.; Stahl, S. S. J. Am. Chem. Soc. 2015, 137, 3454–3457.
10.1021/ja512770u PDF icon Supporting Info

149.

Integration of Anodic and Cathodic Catalysts of Earth-Abundant Materials for Efficient, Scalable CO2 Reduction

Parajuli, R.; Gerken, J. B.; Keyshar, K.; Sullivan, I.; Sivasankar, N.; Teamey, K.; Stahl, S. S.; Cole E. B. Top. Catal. 2015, 58, 57-66.
10.1007/s11244-014-0345-x

148.

Cu-Catalyzed Aerobic Oxidative Three-Component Coupling Route to N-Sulfonyl Amidines via an Ynamine Intermediate

Kim, J.; Stahl, S. S. J. Org. Chem. 2015, 80, 2448–2454.
10.1021/jo5029198 PDF icon Supporting Info

147.

Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry

Osterberg, P. M.; Niemeier, J. K.; Welch, C. J.; Hawkins, J. M.; Martinelli, J. R.; Johnson, T. E.; Root, T. W; Stahl, S. S. Org. Process Res. Dev. 2015, 19, 1537–1543.
10.1021/op500328f

2014


146.

Formic-acid-induced depolymerization of oxidized lignin to aromatics

Rahimi, A.; Ulbrich, A.; Coon, J. J.; Stahl S. S. Nature 2014, 515, 249–252.
10.1038/nature13867 PDF icon Supporting Info

145.

Continuous Flow Aerobic Oxidation Reactions Using a Heterogeneous Ru(OH)x/Al2O3 Catalyst

Mannel, D. S.; Stahl, S. S; Root, T. W. Org. Process Res. Dev. 2014, 18, 1503–1508.
10.1021/op5002676 PDF icon Supporting Info

144.

Ammonolysis of anilides promoted by ethylene glycol and phosphoric acid

Stephenson, N. A.; Gellman, S. H.; Stahl, S. S. RSC Adv. 2014, 4, 46840-46843.
10.1039/C4RA09065A PDF icon Supporting Info

143.

Modular o‑Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

Wendlandt, A. E.; Stahl, S. S. J. Am. Chem. Soc. 2014, 136, 11910–11913.
10.1021/ja506546w PDF icon Supporting Info, File CIF

142.

Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals

Ryland, B. L.; McCann, S. D.; Brunold, T. C.; Stahl, S. S. J. Am. Chem. Soc. 2014, 136, 12166–12173.
10.1021/ja5070137 PDF icon Supporting Info

141.

Palladium catalyzed aryl C–H amination with O2 via in situ formation of peroxide-based oxidant(s) from dioxane

Weinstein, A. B.; Stahl, S. S. Catal. Sci. Technol. 2014, 4, 4301-4307.
10.1039/C4CY00764F PDF icon Supporting Info

140.

Practical Aerobic Oxidations of Alcohols and Amines with Homogeneous Copper/TEMPO and Related Catalyst Systems

Ryland, B. L.; Stahl, S. S. Angew. Chem. Int. Ed. 2014, 53, 8824-8838.
10.1002/anie.201403110

139.

O2-promoted allylic acetoxylation of alkenes: Assessment of “push” versus “pull” mechanisms and comparison between O2 and benzoquinone

Diao,T.; Stahl, S. S. Polyhedron 2014, 84, 96–102.
10.1016/j.poly.2014.06.038

138.

4,5-Diazafluoren-9-one

White, P. B. and Stahl, S. S. e-EROS 2014, 1-3.
10.1002/047084289X.rn01700

137.

Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates

Wang, D.; Izawa, Y.; Stahl, S. S. J. Am. Chem. Soc. 2014, 136, 9914-9917.
10.1021/ja505405u PDF icon Supporting Info

136.

A survey of diverse earth abundant oxygen evolution electrocatalysts showing enhanced activity from Ni-Fe oxides containing a third metal

Gerken, J. B.; Shaner, S. E.; Massé, R. C.; Porubsky, N. J.; Stahl, S. S. Energy Environ. Sci. 2014, 7, 2376-2382.
10.1039/C4EE00436A PDF icon Supporting Info

135.

Organometallics Roundtable 2013–2014

Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbaı̈, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T. Organometallics 2014, 33, 1505-1527.
10.1021/om500253z

134.

Oxidation Adjacent to C=X bonds by Dehydrogenation

Stahl, S. S.; Diao, T. Comp. Org. Synth. 2014, 7, 178-212.
10.1016/B978-0-08-097742-3.00707-2

133.

Inverse Spinel NiFeAlO4 as a Highly Active Oxygen Evolution Electrocatalyst: Promotion of Activity by a Redox-Inert Metal Ion

Chen, J. Y. C.; Miller, J. T.; Gerken, J. B.; Stahl, S. S. Energy Environ. Sci. 2014, 7, 1382-1386.
10.1039/C3EE43811B

132.

Speciation Behavior of Copper(II) Acetate in Simple Organic Solvents – Revealing the Effect of Trace Water

Tsybizova, A.; Ryland, B. L.; Tsierkezos, N.; Stahl, S. S.; Roithová, J.; Schröder, D. Eur. J. Inorg. Chem. 2014, 1407-1412.
10.1002/ejic.201400036 PDF icon Supporting Info

131.

Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst

Wendlandt, A. E.; Stahl, S. S. J. Am. Chem. Soc. 2014, 136, 506-512.
10.1021/ja411692v PDF icon Supporting Info, File CIF

2013


130.

Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems

Hoover, J. M.; Ryland, B. L; Stahl, S. S. ACS Catal. 2013, 3, 2599–2605.
10.1021/cs400689a PDF icon Supporting Info, File CIF

129.

Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NOx Catalyst System

Lauber, M. B.; Stahl, S. S. ACS Catal. 2013, 3, 2612–2616.
10.1021/cs400746m PDF icon Supporting Info

128.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

Steves, J. E.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 15742-15745.
10.1021/ja409241h PDF icon Supporting Info

127.

Synthesis of Vicinal Aminoalcohols by Stereoselective Aza-Wacker Cyclizations: Access to (−)-Acosamine by Redox Relay

Weinstein, A. B.; Schuman, D. P.; Tan, Z. X.; Stahl, S. S. Angew. Chem. Int. Ed. 2013, 51, 11867-11870.
10.1002/anie.201305926 PDF icon Supporting Info

126.

Continuous-Flow Aerobic Oxidation of Primary Alcohols with a Copper(I)/TEMPO Catalyst

Greene, J. F.; Hoover, J. M.; Mannel, D. S.; Root, T. W.; Stahl, S. S. Org. Process Res. Dev. 2013, 17, 1247-1251.
10.1021/op400207f

125.

Aerobic Oxidation of Diverse Primary Alcohols to Methyl Esters with a Readily Accessible Heterogeneous Pd/Bi/Te Catalyst

Powell, A. B.; Stahl, S. S. Org. Lett. 2013, 15, 5072-5075.
10.1021/ol402428e PDF icon Supporting Info

124.

Pd-Catalyzed Semmler–Wolff Reactions for the Conversion of Substituted Cyclohexenone Oximes to Primary Anilines

Hong, W. P.; Iosub, A. V.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 13664–13667.
10.1021/ja4073172 PDF icon Supporting Info, File Supporting Info 2

123.

Cu/Nitroxyl-Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature

Kim, J.; Stahl, S.S. ACS Catal. 2013, 3, 1652-1656.
10.1021/cs400360e PDF icon Supporting Info

122.

Divergence between Organometallic and Single-Electron Transfer Mechanisms in Copper(II)-Mediated Aerobic C–H Oxidation

Suess, A. M.; Ertem, M. Z.; Cramer, C. J.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 9797–9804.
10.1021/ja4026424 PDF icon Supporting Info

121.

Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of PhI(OAc)2 on Aminopalladation Stereoselectivity

Martinez, C.; Wu, Y.; Weinstein, A. B.; Stahl, S. S.; Liu, G.; Muniz, K. J. Org. Chem. 2013, 78, 6309–6315.
10.1021/jo400671q PDF icon Supporting Info, File Supporting Info 2, File Supporting Info 3

120.

Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)2/2-Dimethylaminopyridine: Evidence for the Role of Pd-Nanoparticles

Pun, D.; Diao, T.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 8213–8221.
10.1021/ja403165u PDF icon Supporting Info

119.

Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)2(TFA)2: Evidence for Ligand-Controlled Chemoselectivity

Diao, T.; Pun, D.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 8205–8212.
10.1021/ja4031648 PDF icon Supporting Info

118.

Air Oxidation of Primary Alcohols Catalyzed by Copper(I)/TEMPO. Preparation of 2-Amino-5-bromo-benzaldehyde

Hoover, J. M.; Stahl, S. S. Org. Synth. 2013, 90, 240-250.
PDF icon PDF

117.

Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin

Rahimi, A.; Azarpira, A.; Kim, H.; Ralph, J.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 6415–6418.
10.1021/ja401793n PDF icon Supporting Info

116.

Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for “Click” Coupling

Gerken, J. B.; Rigsby, M. L.; Ruther, R. E.; Perez-Rodriguez, R. J.; Guzei, I. A., Hamers, R. J.; Stahl, S. S. Inorg. Chem. 2013, 52, 2796–2798.
10.1021/ic302827s PDF icon Supporting Info, File Supporting Info 2

115.

Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols

Izawa, Y.; Zheng, C.; Stahl, S. S. Angew. Chem. Int. Ed. 2013, 52, 3672-3675.
10.1002/anie.201209457 PDF icon Supporting Info

114.

Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation

Hoover, J. M.; Ryland, B. L.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 2357-2367.
10.1021/ja3117203 PDF icon Supporting Info

113.

Mechanistic Studies of Wacker-Type Amidocyclization of Alkenes Catalyzed by (IMes)Pd(TFA)2(H2O): Kinetic and Stereochemical Implications of Proton Transfer.

Ye, X.; White, P. B.; Stahl, S. S. J. Org. Chem. 2013, 78, 2083-2090.
10.1021/jo302266t PDF icon Supporting Info

112.

Aerobic Alcohol Oxidation Using a Copper(I)/TEMPO Catalyst System: A Green, Catalytic Oxidation Reaction for the Undergraduate Organic Chemistry Laboratory.

Hill, N. J.; Hoover, J. M.; Stahl, S. S. J. Chem. Educ. 2013, 90, 102-105.
10.1021/ed300368q PDF icon Supporting Info, PDF icon Supporting Info 2, PDF icon Supporting Info 3

2012


111.

Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)2(TFA)2.

Diao, T.; White, P.; Guzei, I.; Stahl, S. S. Inorg. Chem. 2012, 51, 11898-11909.
10.1021/ic301799p PDF icon Supporting Info (Experimental), File Supporting Info (Xtal)

110.

Reconciling the Stereochemical Course of Nucleopalladiation with the Development of Enantioselective Wacker-Type Cyclizations.

Weinstein, A. B.; Stahl, S. S. Angew. Chem. Int. Ed. 2012, 51, 11505-11509.
10.1002/anie.201206702 PDF icon Supporting Info

109.

Catalyst-Controlled Regioselectivity in the Synthesis of Branched Conjugated Dienes via Aerobic Oxidative Heck Reactions.

Zheng, C.; Wang, D.; Stahl, S. S. J. Am. Chem. Soc. 2012, 134, 16496-16499.
10.1021/ja307371w PDF icon 12JACS Zhang SI.pdf

108.

Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Instights into Aryl Transmetalation to Copper(II).

King, A. E.; Ryland, B. L.; Brunold, T. C.; Stahl, S. S. Organometallics 2012, 31, 7948–7957.
10.1021/om300586p PDF icon Supporting Info

107.

Cobalt analogs of Ru-based water oxidation catalysts: Overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O2 evolution.

Rigsby, M. L.; Mandal, S.; Nam, W.; Spencer, L. C.; Llobet, A.; Stahl, S. S. Chem. Sci. 2012, 3, 3058-3062.
10.1039/C2SC20755A PDF icon Supporting Info

106.

Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air.

Hoover, J. M.; Steves, J. E.; Stahl, S. S. Nat. Protoc. 2012, 7, 1161-1167.
10.1038/nprot.2012.057 PDF icon Supporting Info, PDF icon Supporting Info 2

105.

Development of O2-Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation.

Gerken, J. B.; Chen, J. Y. C.; Massé, R. C.; Powell, A. B.; Stahl, S. S. Angew. Chem. Int. Ed. 2012, 51, 6676-6680.
10.1002/anie.201201999 PDF icon Supporting Info

104.

Functionally Diverse Nylon-3 Copolymers from Readily Accessible β-Lactams.

Zhang, J.; Markiewicz, M. J.; Weisblum, B.; Stahl, S. S.; Gellman, S. H. ACS Macro Lett. 2012, 1, 714-717.
10.1021/mz300172y PDF icon Supporting Info

103.

Chemoselective Organocatalytic Aerobic Oxidation of Primary Amines to Secondary Imines.

Wendlandt, A. E.; Stahl, S. S. Org. Lett. 2012, 14, 2850-2853.
10.1021/ol301095j PDF icon Supporting Info

102.

Copper(II)-mediated oxidative cyclization of enamides to oxazoles.

Wendlandt, A. E.; Stahl, S. S. Org. Biomol. Chem. 2012, 10, 3866-3870.
10.1039/C2OB25310K

101.

Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles.

Lu, Z.; Stahl, S. S. Org. Lett. 2012, 14, 1234-1237.
10.1021/ol300030w PDF icon Supporting Info

100.

Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles.

Redford, J. E.; McDonald, R. I.; Rigsby, M. L.; Wiensch, J. D.; Stahl, S. S. Org. Lett. 2012, 14, 1242-1245.
10.1021/ol3000519 PDF icon Supporting Info

99.

Overcoming the "Oxidant Problem": Strategies to Use O2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu).

Campbell, A. N.; Stahl, S. S. Acc. Chem. Res. 2012, 45, 851-863.
10.1021/ar2002045

98.

C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities.

Zhang, Z.; Markiewicz, M. J.; Mowery, B. P.; Weisblum, B.; Stahl, S. S.; Gellman, S. H. Biomacromolecules 2012, 13, 323-331.
10.1021/bm2013058 PDF icon Supporting Info (Experimental), PDF icon Supporting Info (MS)

97.

Direct Aerobic α,β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)2/4,5-Diazafluorenone Catalyst.

Diao, T.; Wadzinski, T. J.; Stahl, S. S. Chem. Sci. 2012, 3, 887-891.
10.1039/C1SC00724F PDF icon Supporting Info

2011


96.

Reversible Alkene Insertion into the Pd-N Bond of Pd(II)-Sulfonamidates and Implications for Catalytic Amidation Reactions.

White, P. B.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 18594-18597.
10.1021/ja208560h PDF icon 11JA White SI1.pdf, PDF icon Supporting Info (NMR)

95.

Copper-Catalyzed Aerobic Oxidative C-H Functionalizations: Trends and Mechanistic Insights.

Wendlandt, A. E.; Suess, A. M.; Stahl, S. S. Angew. Chem. Int. Ed. 2011, 50, 11062-11087.
10.1002/anie.201103945

94.

Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols.

Hoover, J. M.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 16901-16910..
10.1021/ja206230h PDF icon Supporting Info

93.

Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones.

Diao, T.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 14566-14569.
10.1021/ja206575j PDF icon Supporting Info

92.

Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands.

Campbell, A. N.; Meyer, E. B.; Stahl, S. S. Chem. Commun. 2011, 47, 10257-10259.
10.1039/C1CC13632A PDF icon Supporting Info

91.

Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0-14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity.

Gerken, J. B.; McAlpin, J. G.; Chen, J. Y. C.; Rigsby, M. L.; Casey, W. H.; Britt, R. D.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 14431-14442.
10.1021/ja205647m PDF icon Supporting Info

90.

Observation and Mechanistic Study of Facile C-O Bond Formation Between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles.

Huffman, L. M.; Casitas, A.; Font, M.; Canta, M.; Costas, M.; Ribas, X.; Stahl, S. S. Chem. Eur. J. 2011, 17, 10643-10650.
10.1002/chem.201100608 PDF icon Supporting Info

89.

Reaction of O2 with [(-)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H-L]+ "Reductive Elimination" Pathway.

Decharin, N.; Popp, B. V.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 13268-13271.
10.1021/ja204989p PDF icon Supporting Info

88.

Modular "Click" Chemistry for Electrochemically and Photoelectrochemically Active Molecular Interfaces to Tin Oxide Surfaces.

Benson, M. C.; Ruther, R. E.; Gerken, J. B.; Rigsby, M. L.; Bishop, L. M.; Tan, Y.; Stahl, S. S.; Hamers, R. J. ACS Appl. Mater. Interfaces 2011, 3, 3110-3119.
10.1021/am200615r PDF icon Supporting Info

87.

Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols.

Izawa, Y.; Pun, D.; Stahl, S. S. Science 2011, 333, 209-213.
10.1126/science.1204183 PDF icon Supporting Info

86.

Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex.

Huffman, L. M.; Stahl, S. S. Dalton Trans. 2011, 40, 8959-8963.
10.1039/C1DT10463B PDF icon Supporting Info

85.

Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine-Oxazoline Ligands

McDonald, R. I.; White, P. B.; Weinstein, A. B.; Tam, C. P.; Stahl, S. S. Org. Lett. 2011, 13, 2830-2833.
10.1021/ol200784y PDF icon Supporting Info (Experimental), PDF icon Supporting Info (NMR)

84.

Benzoquinone-Promoted Reaction of O2 with a PdII Hydride.

Decharin, N.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 5732-5735.
10.1021/ja200957n PDF icon Supporting Info

83.

Highly Stable Redox-Active Molecular Layers by Covalent Grafting to Conductive Diamond.

Ruther, R. E.; Rigsby, M. L.; Gerken, J. B.; Hogendoorn, S. R.; Landis, E. C.; Stahl, S. S.; Hamers, R. J. J. Am. Chem. Soc. 2011, 133, 5692-5694.
10.1021/ja200210t PDF icon Supporting Info

82.

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications.

McDonald, R. I.; Liu, G.; Stahl, S. S. Chem. Rev. 2011, 111, 2981-3019.
10.1021/cr100371y

81.

Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)2/Pyridine.

Ye, X.; Liu, G.; Popp, B. V.; Stahl, S. S. J. Org. Chem. 2011, 76, 1031-1044.
10.1021/jo102338a PDF icon Supporting Info

80.

O2 insertion into a palladium(II)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways.

Konnick, M. M.; Decharin, N.; Popp, B. V.; Stahl, S. S. Chem. Sci. 2011, 2, 326-330.
10.1039/C0SC00392A

2010


79.

Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization.

Izawa, Y.; Stahl, S. S. Adv. Synth. Catal. 2010, 352, 3223-3229.
10.1002/adsc.201000771 PDF icon Supporting Info

78.

Allylic C-H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy to Achieve Aerobic Catalytic Turnover.

Campbell, A. N.; White, P. B.; Guzei, I. A.; Stahl, S. S. J. Am. Chem. Soc. 2010, 132, 15116-15119.
10.1021/ja105829t PDF icon Supporting Info

77.

Molecular mechansim of acid-triggered aryl-halide reductive elimination in well-defined aryl-CuIII-halide species.

Casitas, A.; Poater, A.; Sola, M.; Stahl, S. S.; Costas, M.; Ribas, X. Dalton Trans. 2010, 39, 10458-10463.
10.1039/C0DT00284D PDF icon Supporting Info

76.

Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands

McDonald, R. I.; Wong, G. W.; Neupane, R. P.; Stahl, S. S.; Landis, C. R. J. Am. Chem. Soc. 2010, 132, 14027-14029.
10.1021/ja106674n PDF icon Supporting Info

75.

Fluoride-Modulated Cobalt Catalysts for Electrochemical Oxidation of Water under Non-Alkaline Conditions.

Gerken, J. B.; Landis, E. C.; Hamers, R. J.; Stahl, S. S. ChemSusChem 2010, 3, 1176-1179.
10.1002/cssc.201000161 PDF icon Supporting Info

74.

Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C-H Bond: Evidence for an Aryl-Copper(III) Intermediate.

King, A. E.; Huffman, L. M.; Casitas, A.; Costas, M.; Ribas, X.; Stahl, S. S. J. Am. Chem. Soc. 2010, 132, 12068-12073.
10.1021/ja1045378 PDF icon Supporting Info

73.

Electronic Structural Comparison of the Reactions of Dioxygen and Alkenes with Nitrogen-Chelated Palladium(0).

Popp, B. V.; Morales, C. M.; Landis, C. R.; Stahl, S. S. Inorg. Chem. 2010, 49, 8200-8207.
10.1021/ic100806w PDF icon Supporting Info

72.

Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides.

McDonald, R. I.; Stahl, S. S. Angew. Chem. Int. Ed. 2010, 49, 5529-5532.
10.1002/anie.200906342 PDF icon Supporting Info

71.

Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation reactions.

Ye, X.; Johnson, M. D.; Diao, T.; Yates, M. H.; Stahl, S. S. Green Chem. 2010, 12, 1180-1186.
10.1039/C0GC00106F PDF icon Supporting Info

70.

Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions.

Casitas, A.; King, A. E.; Parella, T.; Costas, M.; Stahl, S. S.; Ribas, X. Chem. Sci. 2010, 1, 326-330.
10.1039/C0SC00245C PDF icon Supporting Info

69.

Kinetics of Anionic Ring-Opening Polymerization of Variously Substituted β-Lactams: Homopolymerization and Copolymerization.

Zhang, J.; Gellman, S. H.; Stahl, S. S. Macromolecules 2010, 43, 5618-5626.
10.1021/ma1010809 PDF icon Supporting Info

68.

Biophysical Mimicry of Lung Surfactant Protein B by Random Nylon-3 Copolymers

Dohm, M. T.; Mowery, B. P.; Czyzewski, A. M.; Stahl, S. S.; Gellman, S. H.; Barron, A. E. J. Am. Chem. Soc. 2010, 132, 7957-7967.
10.1021/ja909734n PDF icon Supporting Info

2009


67.

Nylon-3 Copolymers that Generate Cell-Adhesive Surfaces Identified by Library Screening.

Lee, M.-R.; Stahl, S. S.; Gellman, S. H.; Masters, K. S. J. Am. Chem. Soc. 2009, 131, 16779-16789.
10.1021/ja9050636 PDF icon Supporting Info

66.

Regioselective Copper-Catalyzed Chlorination and Bromination of Arenes with O2 as the Oxidant.

Yang, L.; Lu, Z.; Stahl, S. S. Chem. Commun. 2009, 6460-6462.
10.1039/B915487F PDF icon Supporting Info

65.

Catalytic Transamidation Reactions Compatible with Tertiary Amide Metathesis under Ambient Conditions.

Stephenson, N. S.; Zhu, J.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc. 2009, 131, 10003-10008.
10.1021/ja8094262

64.

Structure-activity Relationships among Random Nylon-3 Copolymers that Mimic Antibacterial Host-Defense Peptides.

Mowery, B. P.; Lindner, A. H.; Weisblum, B.;Stahl, S. S.; Gellman, S. H. J. Am. Chem. Soc. 2009, 131, 9735-9745.
10.1021/ja901613g PDF icon Supporting Info

63.

Synthesis of Pd(II) Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions.

Scarborough, C. C.; Bergant, A.;Sazamaa, G.T.; Guzeia, I.A.; Spencera, L.C.; Stahl, S. S. Tetrahedron 2009, 65, 5084-5092.
10.1016/j.tet.2009.04.072

62.

Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction.

King, A. E.; Brunold, T. C.; Stahl, S. S. J. Am. Chem. Soc. 2009, 131, 5044-5045.
10.1021/ja9006657 PDF icon Supporting Info

61.

Steric Modulation of Chiral Biaryl Diamines via Pd-Catalyzed Directed C−H Arylation.

Scarborough, C. C.; McDonald, R I.; Hartmann, C.; Sazama, G. T.; Bergant, A.; Stahl, S. S. J. Org. Chem. 2009, 74, 2613-2615.
10.1021/jo802632v PDF icon Supporting Info

60.

Synthesis and Isolation of a Stable, Axially-Chiral Seven-Membered N-Heterocyclic Carbene.

Scarborough, C. C.; Guzei, I. A.; Stahl, S. S. Dalton Trans. 2009, 2284-2286.
10.1039/B902460C PDF icon Supporting Info

59.

Mechanism of Pd(OAc)2/Pyridine Catalyst Reoxidation by O2: Influence of Labile Monodentate Ligands and Identification of a Biomimetic Mechanism for O2 Activation.

Popp, B. V. ; Stahl, S. S. Chem. Eur. J. 2009, 15, 2915-2922.
10.1002/chem.200802311 PDF icon Supporting Info

58.

Access to Poly-β-Peptides with Functionalized Side Chains and End Groups via Controlled Ring-Opening Polymerization of β-Lactams.

Zhang, J.;Kissounko, D. A.; Lee, S. E.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc. 2009, 131, 1589-1597.
10.1021/ja8069192 PDF icon Supporting Info

2008


57.

Synthesis of β-Lactams Bearing Functionalized Side Chains from a Readily Available Precursor.

Lee, M.; Stahl, S. S.; Gellman, S. H. Org. Lett. 2008, 10, 5317-5319.
10.1021/ol802274x PDF icon Supporting Info

56.

Dual Mechanism of Bacterial Lethality for a Cationic Sequence-Random Copolymer that Mimics Host-Defense Antimicrobial Peptides.

Epand, R. F.; Mowery, B. P.; Lee, S. E.; Stahl, S. S.; Lehrer, R. I.; Gellman, S. H.; Epand, R. M. J. Mol. Biol. 2008, 279, 38-50.
10.1016/j.jmb.2008.03.047

55.

Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity.

Hewgley, J. B.; Stahl, S. S.; Kozlowski, M. C. J. Am. Chem. Soc. 2008, 130, 12232-12233.
10.1021/ja804570b PDF icon Supporting Info

54.

Carbon-Nitrogen Bond Formation Involving Well-Defined Aryl-CopperIII Complexes.

Huffman, L. M.; Stahl, S. S. J. Am. Chem. Soc. 2008, 130, 9196-9197.
10.1021/ja802123p PDF icon Supporting Info

53.

Reaction of Molecular Oxygen with a PdII-Hydride To Produce a PdII-Hydroperoxide: Experimental Evidence for an HX-Reductive-Elimination Pathway.

Konnick, M. M.; Stahl, S. S. J. Am. Chem. Soc. 2008, 130, 5753-5762.
10.1021/ja7112504 PDF icon Supporting Info

52.

Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes: Efficient Synthesis of Ynamides

Hamada, T.; Ye, X.; Stahl, S. S. J. Am. Chem. Soc. 2008, 130, 833-835.
10.1021/ja077406x PDF icon Supporting Info (Experimental), PDF icon Supporting Info (NMR)

51.

Discovery and Mechanistic Study of AlIII-Catalyzed Transamidation of Tertiary Amides.

Hoerter, J. M.; Otte, K. M.; Gellman, S. H.; Cui, Q.; Stahl, S. S. J. Am. Chem. Soc. 2008, 130, 647-654.
10.1021/ja0762994 PDF icon Supporting Info

2007


50.

Mimicry of Antimicrobial Host-Defense Peptides by Random Copolymers.

Mowery, B. P.; Lee, S. E.; Kissounko, D. A.; Epand, R. F.; Epand, R. M.; Weisblum, B.; Stahl, S. S.; Gellman, S. H. J. Am. Chem. Soc. 2007, 129, 15474-15476.
10.1021/ja077288d PDF icon Supporting Info

49.

Palladium-Catalyzed Oxidative Amination of Alkenes: Improved Catalyst Reoxidation Enables the Use of Alkene as the Limiting Reagent

Rogers, M. M.; Kotov, V.; Chatwichien, J.; Stahl, S. S. Org. Lett. 2007, 9, 4331-4334.
10.1021/ol701903r PDF icon Supporting Info

48.

The Two-Faced Reactivity of Alkenes: Cis - Versus Trans- Aminopalladation in Aerobic Pd- Catalyzed Intramolecular Aza-Wacker Reactions.

Liu, G.; Stahl, S. S. J. Am. Chem. Soc. 2007, 129, 6328-6335.
10.1021/ja070424u PDF icon Supporting Info

47.

Insertion of Molecular Oxygen into a Pd-Hydride Bond: Computational Evidence for Two Nearly Isoenergetic Pathways.

Popp, B. V.; Stahl, S. S. J. Am. Chem. Soc. 2007, 129, 4410-4422.
10.1021/ja069037v PDF icon Supporting Info

46.

Palladium-Catalyzed Aerobic Oxidative Amination of Alkenes: Development of Intra- and Intermolecular Aza-Wacker Reactions.

Kotov, V.; Scarborough , C. C.; Stahl, S. S. Inorg. Chem. 2007, 46, 1910-1923.
10.1021/ic061997v

45.

Reaction of Molecular Oxygen with an NHC-Coordinated Pd0 Complex: Computational Insights and Experimental Implications.

Popp, B. V.; Wendlandt, J. E.; Landis, C. R.; Stahl, S. S. Angew. Chem. Int. Ed. 2007, 46, 601-604.
10.1002/anie.200603667

44.

Catalytic Metathesis of Simple Secondary Amides.

Bell, C. Kissounko, D. A.; Gellman, S. H.; Stahl, S. S. Angew. Chem. Int. Ed. 2007, 46, 761-763.
10.1002/anie.200603588

43.

TiIV - Mediated Reactions between Primary Amines and Secondary Carboxamides: Amidine Formation Versus Transamidation.

Kissounko, D. A.; Hoerter, J. M.; Guzei, I. A.; Cui, Q.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc. 2007, 129, 1776-1783.
10.1021/ja0650293 PDF icon Supporting Info

42.

Palladium-Catalyzed Oxidation Reactions: Comparison of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants.

Popp, B. V.; Stahl, S. S. In Organometallic Oxidation Catalysis, Meyer, F., Limberg, C. Eds.; Springer: New York, Topics in Organometallic Chemistry 2007, 22, 149-189.
10.1007/3418_039

41.

N-Heterocyclic Carbenes as Ligands for High-Oxidation-State Metal Complexes and Oxidation Catalysis.

Rogers, M. M.; Stahl, S. S. In N-Heterocyclic Carbenes in Transition Metal Catalysis, Glorius, F., Ed.; Springer: New York, Topics in Organometallic Chemistry 2007, 21, 21-46.
10.1007/978-3-540-36930-1_2

2006


40.

Synthesis of Pyrrolidines via Palladium(II)-Catalyzed Aerobic Oxidative Carboamination of Butyl Vinyl Ether and Styrenes with Allyl Tosylamides.

Scarborough , C. C.; Stahl, S. S. Org. Lett. 2006, 8, 3251-3254.
10.1021/ol061057e PDF icon Supporting Info

39.

Highly Regioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and Evidence for cis -Aminopalladation and SN2 C-O Bond Formation.

Liu, G.; Stahl, S. S. J. Am. Chem. Soc. 2006, 128, 7179-7181.
10.1021/ja061706h PDF icon Supporting Info (Experimental), PDF icon Supporting Info (NMR)

38.

Aerobic Intramolecular Oxidative Amination of Alkenes Catalyzed by NHC-Coordinated Palladium Complexes.

Rogers, M. M.; Wendlandt, J. E.; Guzei, I. A.; Stahl, S. S. Org. Lett. 2006, 8, 2257-2260.
10.1021/ol060327q PDF icon Supporting Info (Experimental), PDF icon Supporting Info (NMR)

37.

Reaction of Molecular Oxygen with a PdII-Hydride to Produce a PdII-Hydroperoxide: Acid Catalysis and Implications for Pd-Catalyzed Aerobic Oxidation Reactions.

Konnick, M. M.; Gandhi, B. A.; Guzei, I. A.; Stahl, S. S. Angew. Chem. Int. Ed. 2006, 45, 2904-2907.
10.1002/anie.200600532

36.

Mechanism of AluminumIII-Catalyzed Transamidation of Unactivated Secondary Carboxamides.

Hoerter, J. M.; Otte, K. M.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc. 2006, 128, 5177.
10.1021/ja060331x PDF icon Supporting Info

35.

Mechanism of Pd(OAc)2/DMSO-Catalyzed Aerobic Alcohol Oxidation: Mass-Transfer-Limitation Effects and Catalyst Decomposition Pathways.

Steinhoff, B. A.; Stahl, S. S. J. Am. Chem. Soc. 2006, 128, 4348-4355.
10.1021/ja057914b PDF icon Supporting Info

34.

'Oxidatively-Induced' Reductive Elimination of Dioxygen from an η2-Peroxopalladium(II) Complex Promoted by Electron-Deficient Alkenes.

Popp, B. V.; Stahl, S. S. J. Am. Chem. Soc. 2006, 128, 2804-2805.
10.1021/ja057753b PDF icon Supporting Info

33.

Unexpected Roles of Molecular Sieves in Palladium-Catalyzed Aerobic Oxidation Reactions.

Steinhoff, B. A.; King, A. E.; Stahl, S. S. J. Org. Chem. 2006, 71, 1861-1868.
10.1021/jo052192s

32.

Similarities Between the Reactions of Dioxygen and Alkenes with Palladium(0): Relevance to the Use of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants in Palladium-Catalyzed Oxidation Reactions.

Popp, B. V.; Thorman, J. L.; Stahl, S. S. J. Mol. Catal., A: Chem. 2006, 251, 2-7.
10.1016/j.molcata.2006.02.019

2005


31.

Brønsted Base-Modulated Regioselectivity in the Aerobic Oxidative Amination of Styrene Catalyzed by Palladium.

Timokhin, V. I. ; Stahl, S. S. J. Am. Chem. Soc. 2005, 127, 17888-17893.
10.1021/ja0562806 PDF icon Supporting Info

30.

Palladium-Catalyzed Oxidation of Organic Chemicals with O2.

Stahl, S. S. Science 2005, 309, 1824-1826.
10.1126/science.1114666

29.

Titanium(IV)-Mediated Conversion of Carboxamides to Amidines and Implications for Catalytic Transamidation.

Kissounko, D. A.; Guzei, I. A.; Gellman, S. H.; Stahl, S. S. Organometallics 2005, 24, 5208-5210.
10.1021/om050768y PDF icon Supporting Info

28.

Development of 7-Membered N-Heterocyclic Carbene Ligands for Transition Metals.

Scarborough, C. C.; Popp, B. V.; Guzei, I. A.; Stahl, S. S. J. Organomet. Chem. 2005, 690, 6143-6155.
10.1016/j.jorganchem.2005.08.022

27.

PalladiumII Complexes Possessing a Seven-Membered N-Heterocyclic Carbene Ligand.

Scarborough, C. C.; Grady, M. J. W.; Guzei, I. A.; Gandhi, B. A.; Bunel, E. E.; Stahl, S. S. Angew. Chem. Int. Ed. 2005, 44, 5269-5272.
10.1002/anie.200501522

26.

Effects of Side Chain Configuration and Backbone Spacing on the Gene Delivery Properties of Lysine-Derived Cationic Polymers.

Eldred, S. E.; Pancost, M. R.; Otte, K. M.; Rozema, D.; Stahl, S. S.; Gellman, S. H. Bioconjugate Chem. 2005, 16, 694-699.
10.1021/bc050017c

25.

Aerobic Oxidative Amination of Unactivated Alkenes Catalyzed by Palladium.

Brice, J. L.; Harang, J. E.; Timokhin, V. I.; Anastasi, N. R.; Stahl, S. S. J. Am. Chem. Soc. 2005, 127, 2868-2869.
10.1021/ja0433020 PDF icon Supporting Info

2004


24.

Insights into the Spin-Forbidden Reaction between L2Pd0 and Molecular Oxygen.

Landis, C. R.; Morales, C. M.; Stahl, S. S. J. Am. Chem. Soc. 2004, 126, 16302-16303.
10.1021/ja044674b PDF icon Supporting Info

23.

"Inverse-Electron-Demand" Ligand Substitution: Experimental and Computational Insights into Olefin Exchange at Palladium(0).

Popp, B. V.; Thorman, J. L.; Morales, C. M.; Landis, C. R.; Stahl, S. S. J. Am. Chem. Soc. 2004, 126, 14832-14842.
10.1021/ja0459734 PDF icon Supporting Info

22.

Mechanistic Characterization of Aerobic Alcohol Oxidation Catalyzed by Pd(OAc)2 / Pyridine Including Identification of the Catalyst Resting State and the Origin of Non-Linear [Catalyst] Dependence.

Steinhoff, B. A.; Guzei, I. A.; Stahl S. S. J. Am. Chem. Soc. 2004, 126, 11268-11278.
10.1021/ja049962m PDF icon Supporting Info

21.

Characterization of Peroxo and Hydroperoxo Intermediates in the Aerobic Oxidation of N-Heterocyclic-Carbene-Coordinated Palladium(0).

Konnick, M. M.; Guzei, I. A.; and Stahl, S. S. J. Am. Chem. Soc. 2004, 126, 10212-10213.
10.1021/ja046884u PDF icon Supporting Info

20.

Palladium Oxidase Catalysis: Selective Oxidation of Organic Chemicals via Direct Dioxygen-Coupled Catalytic Turnover.

Stahl, S. S. Angew. Chem. Int. Ed. 2004, 43, 3400-3420.
10.1002/anie.200300630

19.

Formation of Enamides via Palladium(II)-Catalyzed Vinyl Transfer from Vinyl Ethers to Nitrogen Nucleophiles.

Brice, J. l.; Meerdink, J. M.; Stahl, S. S. Org. Lett. 2004, 6, 1845-1848.
10.1021/ol0494360 PDF icon Supporting Info

2003


18.

Dioxygen-Coupled Oxidative Amination of Styrene.

Timokhin, V. I.; Anastasi, N. R.; Stahl, S. S. J. Am. Chem. Soc. 2003, 125, 12996-12997.
10.1021/ja0362149 PDF icon Supporting Info

17.

Catalytic Transamidation under Moderate Conditions.

Eldred, S. E.; Stone, D. A.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc. 2003, 125, 3422-3423.
10.1021/ja028242h

16.

'Inverse-Electron-Demand' Ligand Substitution in Palladium(0) Olefin Complexes.

Stahl, S. S.; Thorman, J. L.; de Silva, N.; Guzei, I. A.; Clark, R. W. J. Am. Chem. Soc. 2003, 125, 12-13.
10.1021/ja028738z PDF icon Supporting Info

2002


15.

The Wisconsin Schlenk Line: Incorporation of an Ergonomic Greaseless Three-Way Valve Design.

Drier, T. O.; Stahl, S. S. Fusion 2002, 3, 25-27.

14.

Ligand-Modulated Palladium Oxidation Catalysis: Mechanistic Insights into Aerobic Alcohol Oxidation with the Pd(OAc)2 / Pyridine Catalyst System.

Steinhoff, B. A.; Stahl, S. S. Org. Lett. 2002, 4, 4179-4181.
10.1021/ol026988e PDF icon Supporting Info

13.

Mechanistic Study of Alcohol Oxidation by the Pd(OAc)2/O2/DMSO Catalyst System and Implications for the Development of Improved Aerobic Oxidation Catalysts.

Steinhoff, B. A.; Fix, S. R.; Stahl, S. S. J. Am. Chem. Soc. 2002, 124, 766-767.
10.1021/ja016806w PDF icon Supporting Info

12.

Efficient Intramolecular Oxidative Amination of Olefins through Direct Dioxygen-Coupled Palladium Catalysis.

Fix, S. R.; Brice, J. L.; Stahl, S. S. Angew. Chem. Int. Ed. 2002, 41, 164-166.
10.1002/1521-3773(20020104)41:1<164::AID-ANIE164>3.0.CO;2-B

2001


11.

Oxygenation of Nitrogen-Coordinated Palladium(0): Synthetic, Structural and Mechanistic Studies and Implications for Aerobic Oxidation Catalysis.

Stahl, S. S.; Thorman, J. L.; Nelson, R. C.; Kozee, M. A. J. Am. Chem. Soc. 2001, 123, 7188-7189.
10.1021/ja015683c PDF icon Supporting Info

Before UW-Madison

Oxygen Kinetic Isotope Effects in Methane Monooxygenase.

Dioxygen and Alkane Activation by Iron-Containing Enzymes.

Mechanistic Studies of the Reaction of Reduced Methane Monooxygenase Hydroxylase with Dioxygen and Substrates.

Homogeneous Oxidation of Alkanes by Electrophilic Late Transition Metals.

Investigation of the Factors Affecting the Stability of Dihydrogen Adducts of Platinum(II).

Alkylplatinum(II) Intermediates in C-H Activation by Platinum Complexes in Aqueous Solution.

Exploring the Mechanism of Aqueous C-H Activation by Pt(II) through Model Chemistry: Evidence for the Intermediacy of Alkylhydridoplatinum(IV) and Alkane σ-Adducts.

Formation and Reductive Elimination of a Hydridoalkylplatinum(IV) Intermediate upon Protonolysis of an Alkylplatinum(II) Complex.

C-H Activation by Aqueous Platinum Complexes: A Mechanistic Model.

Oxidation of Zeise's Salt by [PtCl6]2- : A Mechanistic Model for Hydrocarbon Oxidation.

Patents

  1. "Conversion of Alcohols to Alkyl Esters and Carboxylic Acids Using Hetergeneous Palladium-Based Catalyst."
    Stahl, S.S.; Powell, A.B.; Root, T.W.; Mannel, D.S.; Ahmed, M.S. Patent No.: US 9,593,064 B2, March 14, 2017.
  2. "Cobalt Oxyfluoride Catalysts for Electrolytic Dissociation of Water."
    Gerken, J. B.; Stahl, S. S. Patent No.: US 8,192,609 B2, June 5, 2012
  3. "Poly-β-Peptides From Functionalized β-Lactam Monomers and Antibacterial Compositions Containing Same."
    Stahl, S. S.; Gellman, S. H.; Lee, S. E.; Ilker, M. F.; Weisblum, B.; Kissounko, D. A. U. S. Patent 20070087404, April 19, 2007
  4. "Seven-Membered Heterocyclic Carbenes and their Metal Complexes."
    Stahl, S. S.; Scarborough , C. C. EP20060733854, January 23, 2008.
  5. "Catalytic Transamidation and Amide Metathesis under Moderate Conditions."
    Stahl, S. S.; Gellman, S. H.; Eldred, S. E. U.S. Patent 7,154,004, December 26, 2006.